You can always connect a USB stick or card reader with an SD card via USB-OTG
I will recommend you do use a phone that still receives security updates (Not EoL) because I don't want you to lose out on security just to deGoogle.
If you are strict on having an SD card slot and your phone is still receiving support, you should use StockOS to receive firmware updates as soon as possible. If the phone you decide to get is EoL, the least bad option would be DivestOS (fork of LineageOS)
The desktop security model is insecure in general. Phone OSes are much more secure.
Reasonable desktop OS to use is Qubes, Fedora, MacOS, ChromeOS, or Windows pro/enterprise (hardened)
Phones are much more secure especially the Pixel 8/pro with MTE immensely reducing remote exploitation. GrapheneOS is the only distro that enables MTE by default and recently implemented it in their Vanadium browser.
Secure phones (secure elements are important): IPhones and Pixels (GrapheneOS or stock)
Also yes, Chromium is much more secure on Linux than Gecko based browsers because of its great internal sandboxing and site isolation. Firefox on Windows is catching up though, but still bad on desktop Linux and android.
This all doesn't matter if you're running an EoL device. Make sure your receiving official security and firmware updates.
that's about it